Search Minerals Announces Metallurgical Breakthrough for Rare Earth Recovery
TORONTO, July 23, 2014 /PRNewswire/ – Search Minerals Inc. (“Search” or the “Company“) (TSXV: SMY) and its wholly-owned subsidiary, Alterra Resources Inc.,
are pleased to announce the development of a simplified metallurgical
process tested on a bulk sample from the Company’s Foxtrot Project (“Foxtrot” or the “Project“), located in the Port Hope Simpson Rare Earth Element District in SE
Labrador, to produce a high grade rare earth elements (“REE“) product for refining. A patent application has been lodged with the
United States Patent Office to protect the Company’s ownership of this
technology. Support was received from the Research & Development
Corporation (“RDC“) of Newfoundland and Labrador and from the Atlantic Canada
Opportunities Agency (“ACOA“) for this development. Testing was completed by SGS Canada Inc. (“SGS“).
-- A simple metallurgical treatment of coarse-crushed Foxtrot ore has been demonstrated to give high overall extractions of rare earths (73.1 to 78.9% for La-Er). There is no longer any need for grinding, flotation, gravity or magnetic separation to treat the Foxtrot ore. -- A crushed sample of Foxtrot ore (6 mesh, 3.35 mm) was treated by acid (200 °C) and water leaching to extract rare earths. Extraction from the ore ranged from 73.8 to 80% for La-Er and 55.9 to 69.9% for Tm-Lu. -- The leachate was purified by pH adjustment, and then precipitated to give a mixed carbonate precipitate. -- The mixed carbonate was further refined by acid leaching, oxalate re-precipitation and calcination to produce a high grade rare earth oxide ("REO") containing low levels of key impurities (including thorium) for refining to separate rare earth products. -- A larger demonstration test of the Company's technology is scheduled for Q3 2014 at SGS. -- Search is expected to enter into discussions with interested parties for the refining of the high grade rare earth oxide product starting in Q3 2014. -- A United States Provisional Patent has been filed to protect the new rare earth recovery process.
Stephen Keith, President and CEO of Search, commented on the findings,
“We are very pleased with these developments, as they are expected to
significantly lower the Foxtrot operating and capital costs. This
innovative technology should also allow the Company to move the Foxtrot
Project more quickly to development, resulting in long-term value
growth for the Company.”
A metallurgical sample of the Foxtrot ore (channel sample) was subjected
to a simple process of crushing and treatment with concentrated
sulfuric acid. The acid treated ore was water leached to extract REEs
into the solution. The leached solids were filtered and washed. The
leachate containing REEs was purified by a series of steps to produce a
purified REO. The key steps included purification by pH adjustment
with magnesium carbonate, precipitation of REEs with sodium carbonate,
selective re-extraction of the REEs with hydrochloric acid,
re-precipitation of REEs with oxalic acid and, finally, calcination of
the rare earth oxalate to produce a REO for refining.
The results of the acid treatment/water leach are shown in Table 1. A
sample of Foxtrot ore was crushed to 6 mesh (approximately 3 mm in
size) and treated with 100 kg of H(2)So(4) per tonne of ore at 200 °C for two hours. The acid treated ore was
then leached with water at 90 °C for 24 hours, followed by filtration
and washing to recover a filtrate. The extraction of impurity elements
like iron (Fe) and aluminum (Al) were controlled to 5.5 and 4.6%
________________________________________________________________________________________________________ | La | Ce | Pr | Nd | Sm | Eu | Gd | Tb | Dy | Ho | Y | Er | Tm | Yb | Lu | |______|______|______|______|______|______|______|______|______|______|______|______|______|______|______| | 76.7 | 78.1 | 79.6 | 80.0 | 79.6 | 79.1 | 78.4 | 79.3 | 77.5 | 76.0 | 77.0 | 73.8 | 69.9 | 64.9 | 55.9 | |______|______|______|______|______|______|______|______|______|______|______|______|______|______|______|
Table 1. REE Extractions (%) from Foxtrot Ore using Search’s Simplified
The water leachate was treated with magnesium carbonate to precipitate
impurities as a solid residue. The purified solution was then treated
with sodium carbonate to precipitate a mixed rare earth carbonate. The
loss of REEs in the purification process was low and the precipitation
efficiency was high. Table 2 summarizes the overall recoveries of REEs
using the simplified process.
________________________________________________________________________________________________________ | La | Ce | Pr | Nd | Sm | Eu | Gd | Tb | Dy | Ho | Y | Er | Tm | Yb | Lu | |______|______|______|______|______|______|______|______|______|______|______|______|______|______|______| | 75.9 | 77.3 | 78.9 | 79.3 | 78.9 | 78.4 | 77.6 | 78.4 | 78.7 | 75.3 | 76.3 | 73.1 | 69.2 | 64.3 | 55.4 | |______|______|______|______|______|______|______|______|______|______|______|______|______|______|______|
Table 2. Overall REE Recovery (%) from Foxtrot Ore to Mixed Carbonate
Precipitate using Search’s Simplified Process
The rare earth carbonate precipitate was purified by selective
releaching in hydrochloric acid, precipitation with oxalic acid and
calcination (to convert the precipitate to a REO). The provisional
analysis for the mixed REO is shown in Table 3 (Chemical Analysis) and
Table 4 (Impurity Analysis).
________________________ | REO | Analysis (%) | |_________|______________| | La2O3 | 14.66 | |_________|______________| | CeO2 | 34.89 | |_________|______________| | Pr6O11 | 3.90 | |_________|______________| | Nd2O3 | 15.28 | |_________|______________| | Sm2O3 | 2.19 | |_________|______________| | Eu2O3 | 0.12 | |_________|______________| | Gd2O3 | 2.11 | |_________|______________| | Tb4O7 | 0.33 | |_________|______________| | Dy2O3 | 1.85 | |_________|______________| | Ho2O3 | 0.36 | |_________|______________| | Y2O3 | 10.02 | |_________|______________| | Er2O3 | 0.98 | |_________|______________| | Tm2O3 | 0.12 | |_________|______________| | Yb2O3 | 0.61 | |_________|______________| | Lu2O3 | 0.07 | |_________|______________| | | | |_________|______________| | TREO* | 87.5 | |_________|______________| | LREO** | 68.7 | |_________|______________| | HREO*** | 18.8 | |_________|______________|
Table 3. Chemical Analysis (%) of the REO using ICP and XRF
(Inductively Coupled Plasma and X-Ray Fluorescence)
*TREO refers to the sum of all REs and Y as oxides
**LREO refers to the sum of La, Ce, Pr, Nd oxides
***HREO refers to the sum of Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and
__________________________ | Element | Analysis (g/t) | |_________|________________| | Th | 6.5 | |_________|________________| | U | 48.5 | |_________|________________| | Si | <5 | |_________|________________| | Al | <2000 | |_________|________________| | Fe | 744 | |_________|________________| | Mg | 316 | |_________|________________| | Ca | <2000 | |_________|________________| | Na | <1000 | |_________|________________| | K | <1000 | |_________|________________| | Ti | <40 | |_________|________________| | P | <40 | |_________|________________| | Mn | 64 | |_________|________________| | Zn | 1490 | |_________|________________| | F (%) | 0.15 | |_________|________________| | C (%) | 0.02 | |_________|________________|
Table 4. Impurity Analysis of the REO
Note that fluoride (F) and carbon (C) are reported as (%)
This process is a significant improvement over the earlier Foxtrot work
reported on May 9, 2012 (see “Search Minerals Announces Successful Metallurgical Testing of Foxtrot
Project Sample to Recover a 55.48% TREO + Y2O3 Product (46.99% TREE+Y)
with Overall Average Recovery of 78.8%“). The steps of grinding, flotation, gravity and magnetic separation
to produce an ore concentrate are no longer required to process the
Foxtrot ore. The coarse crushed ore is directly treated with small
amounts of acid in a heated pug mill, a conventional mixing device,
prior to water leaching.
A larger scale demonstration test will be performed at SGS in the Q3
2014. The test will provide data for engineering scale-up,
optimization of process parameters and production of a multi-kilogram
REO product for sampling to potential refining partners for evaluation.
Search is now engaging with potential refining partners to assess the
technical and commercial requirements for refining the high grade REO
product from the Foxtrot ore. Following completion of the demonstration
of the Search’s process, it is expected that the revised economics of
the Project will be developed by an independent engineering contractor.
Search Minerals would like to recognize the support, totalling
C$225,000, made available equally from RDC and ACOA to assist in the
development of innovative technologies for the recovery and refining of
REEs from ore mined at the Project.
Dr. David Dreisinger, Ph.D., P.Eng., is the Company’s Vice President,
Metallurgy and Qualified Person for the purposes of NI 43-101. Dr.
Dreisinger has reviewed and approved the technical disclosure contained
in this news release as applicable. The company will endeavour to meet
high standards of integrity, transparency, and consistency in reporting
technical content, including geological and assay (e.g., REE) data.
About The Foxtrot Project
The Foxtrot Project in the Port Hope Simpson Rare Earth Element District
in southeastern Labrador has a positive Preliminary Economic Assessment
indicating a Life-of-Mine plan with indicated mineral resources of 5.3
Mt, at an average grade of 0.89% Total Rare Earth Elements (“TREE“), could be mined over 10 years, including open pit mining TREE for the
first 3.5 years and underground mining thereafter. Production at the
Project is anticipated to total 38 million kg of payable rare earth
material. Indicated mineral resources are estimated to total 9.23 Mt at
0.88% TREE (or 1.07% Total Rare Earth Oxides (“TREO“)), and inferred mineral resources are estimated to total 5.17 Mt at
0.77% TREE (or 0.93% TREO).
Pending successful completion of a financing, Search is planning an
exploration program to further map and sample Foxtrot-like
mineralization throughout the Fox Harbour volcanic belt (see “Search Minerals Announces Ten New Foxtrot-like REE Prospects in 64
km-long Mineralized Belt in SE Labrador“, October, 30, 2013) and to prioritize targets for a small exploration
drilling program. The aim of this program is to discover/document
additional Foxtrot-like deposits in close proximity to the Foxtrot
Deposit, and to add to the Foxtrot resource (currently 9.3 million
tonnes Indicated at 189 ppm Dy, and 5.2 million tonnes Inferred at 176
ppm Dy (see “Search Minerals Phase III Drilling Increases Foxtrot REE Project
Resource Estimate by 55% of Similar Grade,” November 1, 2012).
About Search Minerals
Search Minerals Inc. (TSXV: SMY) is a TSX Venture Exchange listed
company focused on creating value through finding and developing
mineral assets with growing demand and constrained or restricted
supply, and with increasing use in innovative technologies. The Company
is actively pursuing opportunities and partnerships in critical metals,
including, but not limited to, tin, tungsten, dysprosium and neodymium,
prioritizing projects that can be partnered, funded and developed in a
relatively short period of time, in strategic, friendly jurisdictions.
Search is the discoverer of the Port Hope Simpson REE District, a highly
prospective light and heavy REE belt located in southeast Labrador,
where the Company controls a dominant land position in a belt 70 km
long and up to 8 km wide. In addition, Search holds a number of
additional mineral prospects in Newfoundland and Labrador in its
portfolio, including claims in the Strange Lake Complex (where Quest
Rare Minerals has a Joint Venture with Search); and at the Red Wine
Complex (where Great Western Minerals Group has a Joint Venture with
Neither the TSX Venture Exchange nor its Regulation Services Provider
(as that term is defined in the policies of the TSX Venture Exchange)
accepts responsibility of the adequacy or accuracy of this release.
Cautionary Statement Regarding Forward-Looking Information:
This news release includes certain “forward-looking statements” under
applicable Canadian securities legislation that are not historical
facts. Forward-looking statements involve risks, uncertainties, and
other factors that could cause actual results, performance, prospects,
and opportunities to differ materially from those expressed or implied
by such forward-looking statements. The preliminary economic assessment
is preliminary in nature, it includes inferred mineral resources that
are considered too speculative geologically to have the economic
considerations applied to them that would enable them to be categorized
as mineral reserves and there is no certainty that the preliminary
economic assessment will be realized. Mineral resources that are not
mineral reserves do not have demonstrated economic viability.
Forward-looking statements are necessarily based on a number of
estimates and assumptions that, while considered reasonable, are
subject to known and unknown risks, uncertainties and other factors
which may cause actual results and future events to differ materially
from those expressed or implied by such forward-looking statements.
Such factors include, but are not limited to: general business,
economic and social uncertainties; litigation, legislative,
environmental and other judicial, regulatory, political and competitive
developments; and those additional risks set out in Search’s public
documents filed on SEDAR at www.sedar.com. Although Search believes that the assumptions and factors used in
preparing the forward-looking statements are reasonable, undue reliance
should not be placed on these statements, which only apply as of the
date this news release and no assurance can be given that such events
will occur in the disclosed time frames or at all. Except where
required by law, Search disclaim any intention or obligation to update
or revise any forward-looking statement, whether as a result of new
information, future events, or otherwise.
SOURCE Search Minerals Inc.