February 17, 2010
Compostable Plastics Have A Sweet Ending
Food packaging and other disposable plastic items could soon be composted at home along with organic waste thanks to a new sugar-based polymer.
The degradable polymer is made from sugars known as lignocellulosic biomass, which come from non-food crops such as fast-growing trees and grasses, or renewable biomass from agricultural or food waste.
It is being developed at Imperial College London by a team of Engineering and Physical Sciences Research Council scientists led by Dr Charlotte Williams.
The search for greener plastics, especially for single use items such as food packaging, is the subject of significant research worldwide. "It's spurred on not only from an environmental perspective, but also for economic and supply reasons," explains Dr Williams.
Around 7% of worldwide oil and gas resources are consumed in plastics manufacture, with worldwide production exceeding 150 million tons per year. Almost 99% of plastics are formed from fossil fuels.
"Our key breakthrough was in finding a way of using a non-food crop to form a polymer, as there are ethical issues around using food sources in this way," said Williams. Current biorenewable* plastics use crops such as corn or sugar beet.
"For the plastic to be useful it had to be manufactured in large volumes, which was technically challenging. It took three-and-a-half years for us to hit a yield of around 80% in a low energy, low water use process," explains Dr Williams.
This is significant as the leading biorenewable plastic, polylactide, is formed in a high energy process requiring large volumes of water. In addition, when it reaches the end of its life polylactide must be degraded in a high-temperature industrial facility.
In contrast, the oxygen-rich sugars in the new polymer allow it to absorb water and degrade to harmless products "“ meaning it can be tossed on the home compost heap and used to feed the garden.
Because the new polymer can be made from cheap materials or waste products it also stacks up economically compared to petrochemical-based plastics.
The polymer has a wide range of properties, laying the field open for a larger number of applications other than biorenewable plastic packaging. Its degradable properties make it ideal for specialized medical applications such tissue regeneration, stitches and drug delivery. The polymer has been shown to be non-toxic to cells and decomposes in the body creating harmless by-products.
The team "“ including commercial partner BioCeramic Therapeutics, which was set up by Professor Molly Stevens and colleagues at Imperial "“ are investigating ways of using the material as artificial scaffolds for tissue regeneration. They are also focusing on exploiting the degradable properties of the material to release drugs into the body in a controlled way.
Now the team is focused on developing the specific material characteristics needed for the packaging and medical areas.
"The development of the material is very promising and I'm optimistic that the technology could be in use within two to five years," says Williams, who is already working with a number of commercial partners and is keen to engage others interested in the material.
Biorenewable plastics are materials whose feedstock material (monomer) comes from renewable resources. The leading example is poly(lactic acid) which derives from lactic acid, produced by fermentation of corn or sugar beet. These biorenewable plastics are different to biopolymers, which are naturally occurring polymers such as starch or cellulose (note that these are not plastic materials).
The chemical name for the compostable polymer is Poly(acetic acid-5-acetoxy-6-oxo-tetrahydro-pyran-2-yl-methyl ester) and copoly(lactic acid-ran-acetic acid-5-acetoxy-6-oxo-tetrahydro-pyran-2-yl-methyl ester).
Research leader Dr Charlotte Williams is a champion of the widespread application of biomass to make fuels and materials. She has published a highly cited article in science magazine highlighting the challenges associated with converting plants to fuels and products. She won a 2009 Royal Society of Chemistry Early Career Award for her work in this area. The research is being carried out in collaboration with Prof. Molly Stevens, an expert in the application of degradable plastics in medicine. Her research has recently been recognized by the IUPAC creativity in polymer science prize.
The polymer was discovered and developed by Dr Min Tang and Dr Anita Haider in their doctoral research. Dr Tang continues to develop the materials.
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