IBM Scientists Directly Measure Charge States of Atoms Using an Atomic Force Microscope
Nanoscience milestone opens up new possibilities in molecular electronics
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Measuring with the precision of a single electron charge and nanometer lateral resolution, researchers succeeded in distinguishing neutral atoms from positively or negatively charged ones. This represents a milestone in nanoscale science and opens up new possibilities in the exploration of nanoscale structures and devices at the ultimate atomic and molecular limits. These results hold potential to impact a variety of fields such as molecular electronics, catalysis or photovoltaics.
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To conduct these experiments, researchers used a combined scanning tunneling microscope (STM) and atomic force microscope (AFM) operated in vacuum at very low temperature (5 Kelvin) to achieve the high stability necessary for these measurements.
The AFM in principle uses a sharp tip to measure the attractive forces between the tip and the atoms on a substrate. In the setup of the present work, the AFM uses a qPlus force sensor consisting of a tip mounted on one prong of a tuning fork, the other prong being fixed. The tuning fork, which is like those found in ordinary wristwatches, is actuated mechanically and oscillates with amplitudes as small as 0.02 nanometer — which is about one-tenth of an atom’s diameter. As the AFM tip approaches the sample, the resonance frequency of the tuning fork is shifted due to the forces acting between sample and tip. By scanning the tip over a surface and measuring the differences in the frequency shift, a precise force map of the surface can be derived.
The extremely stable measurement conditions were crucial for sensing the minute differences in the force caused by the charge state switching of single atoms. The difference between the force of a neutral gold atom and that of a gold atom charged with an additional electron, for example, was found to be only about 11 piconewton, measured at the minimum distance to the tip of about half a nanometer above the atom. The measurement accuracy of these experiments is better than 1 piconewton — which is equal to the gravitational force that two adults exert on each other over a distance of more than half a kilometer. Moreover, by measuring the variation of the force with the voltage applied between tip and sample, the scientists were able to distinguish positively from negatively charged single atoms.
This breakthrough is yet another crucial advance in the field of atomic-scale science. In contrast to the STM, which can be used only on conducting materials, the AFM is independent of conductivity and can be used for investigating materials of all kinds, most importantly insulators. In the field of molecular electronics, which aims at using molecules as functional building blocks for future computing devices, as well as for single-electron devices, an insulating substrate is needed in order to avoid the leakage of electrons. This makes noncontact atomic force microscopy the investigation method of choice.
“The AFM with single-electron-charge sensitivity is a powerful tool to explore the charge transfer in molecule complexes, providing us with crucial insights and new physics to what might one day lead to revolutionary computing devices and concepts,” explains
This achievement follows a string of remarkable scientific advances achieved by IBM scientists in recent years and represents a fundamental step towards building computing elements at the molecular scale–computing elements that are expected to be vastly smaller, faster and more energy-efficient than today’s processors and memory devices.
Using the qPlus AFM, a team at the IBM Almaden Research Center was the first to measure in 2008 the force necessary to move an atom over a surface, paving the way for the present experiment. In 2007, Gerhard Meyer’s team at IBM’s Zurich Lab demonstrated a single-molecule switch that can operate flawlessly without disrupting the molecule’s outer frame or shape. In 2004, the same group controllably manipulated the charge state of individual atoms using an STM. By inducing voltage pulses through the STM tip, they succeeded in charging an individual atom on a thin insulating film with an additional electron. Importantly, the negatively charged atom remained stable until a voltage pulse with the opposite bias was applied via the STM tip. This is the method used by scientists in the present experiments to charge the individual atoms.
IBM and Nanotechnology
IBM has been a pioneer in nanoscience and nanotechnology ever since the development of the STM in 1981 by IBM Fellows Gerd Binnig and
The scientific paper entitled “Measuring the Charge State of an Adatom with Noncontact Atomic Force Microscopy” by L. Gross, F. Mohn, P. Liljeroth, J. Repp, F. J. Giessibl, and G. Meyer, was published in Science, Volume 324, Issue 5933, pp. 1428 – 1431 (
See also the Science perspectives article entitled “Novel Probes for Molecular Electronics” by E. Meyer and T. Glatzel, published in Science, Volume 324, Issue 5933, pp. 1397 – 1398 (12.
High-resolution images can be found here: http://www.zurich.ibm.com/news/09/afm.html
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